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Nonlinear Crystals

In 2016, for the first time in the world, a new nonlinear crystal of high optical quality BaGa2GeSe6 was obtained, which has nonlinearity coefficients d11 = 23.6, d22 = 18.5, d31 = 18.3 pm/V. Transmission range 0.522–18 microns, band gap width 2.38 eV, resistance to laser radiation 5.35 J/cm2.  BGGSe is a nonlinear ...

Specifications

Crystal Type: N/A
Phase Mathcing Type: Not Applicable
Mounting: Unmounted
Width: 10 mm
Height: 10 mm
AgGaS2 is a negative uniaxial crystal: no > ne. The symmetry class is tetragonal D2d, spatial group D2 d12. The transparency range is 0.47–12.5 microns. The nonlinear coefficient d36 = 12.5 pm/V. Birefringence of ne − no = 0.0537 at a wavelength of 1.06 microns. The laser resistance is 20 MW/cm2.

Specifications

Crystal Type: AgGaS2 (Silver Gallium Sulfide)
Phase Mathcing Type: Not Applicable
Mounting: N/A
Width: 12 mm
Height: 12 mm
BaGa4Se7 (BGSe) is the latest promising chalcogenide crystal with large nonlinear optical coefficients (d11 = 24.3 pm/V and d13 = 20.4 pm/V) and a wide transparency range of 0.47—18 microns [18-22]. The tuning range of the BGSe ORO with a 2.1 µm pump for type 1 was 3-5 microns, and the maximum output power reached 1.55 ...

Specifications

Crystal Type: N/A
Phase Mathcing Type: Not Applicable
Mounting: Unmounted
Width: 12 mm
Height: 12 mm
Generation was obtained at two transitions of the Dy3+ 6H11/2 — 6H13/2 and 6H9/2 — 6H11/2 ion according to a cascade scheme. The pumping was carried out by the YAG-Nd3+ laser at a wavelength of 1.38 microns. Measurement of the lifetime of levels 6H9/2, 6H11/2 and 6H13/2 showed that it is equal to 160 microseconds, 2 ms ...

Specifications

Crystal Type: N/A
Phase Mathcing Type: Not Applicable
Mounting: N/A
Width: 10 mm
Height: 10 mm
BaGa4S7(BGS) crystals were grown by the Bridgman-Stockbarger method in the laboratory, and its selenium-containing analogue BaGa4Se7(BGSe) was obtained for the first time with dimensions large enough to measure the coefficients of dispersion and refraction, which is a prerequisite for predicting the features of phase interaction. ...

Specifications

Crystal Type: N/A
Phase Mathcing Type: Not Applicable
Mounting: Unmounted
Width: 10 mm
Height: 10 mm
Focusing on nonlinear frequency mixing, HCP develops PPMgO:LN bulk chips and PPMgO:LN waveguide chips on the basis of Periodically Poled Lithium Niobate (LiNbO3), Lithium Tantalate (LiTaO3), MgO:PPLN (5mol.%), and MgO:PPLT (8mol.%). In general principle, PPLN bulk chips are easy to manage and sustain higher power (Watts level), while ...

Specifications

Crystal Type: LiNbO3 (Lithium Niobate), LT (LiTaO3)
Phase Mathcing Type: Type I, Type II
Mounting: Mounted, Unmounted
Width: 0.1 mm
Height: 0.1 mm
The LBO Crystal, or Lithium Triborate (LiB3O5), is a highly esteemed nonlinear optical crystal known for its exceptional properties. With a wide transparency range spanning from 210 nm to 2300 nm, LBO crystals are versatile and suitable for a variety of optical applications. Their moderately nonlinear coupling and high damage ...

Specifications

Crystal Type: LBO (Lithium Triborate)
Phase Mathcing Type: Type II
Mounting: Unmounted
Width: 30 mm
Height: 40 mm
Lithium Triborate (LBO) Crystals are renowned for their exceptional optical properties, making them a preferred choice in various high-power laser applications. These crystals are characterized by their high damage threshold, which ensures durability and reliability even under intense laser exposure. This makes them particularly ...

Specifications

Crystal Type: LBO (Lithium Triborate)
Phase Mathcing Type: Not Applicable
Width: 3 mm
Height: 15 mm
Length: 3 mm
This is a BaGa2GeSe6 Nonlinear Crystal. It has a nonlinear coefficients of d11 = +23,6, d22 = -18,5, d31 = +18,3 pm/W. Transmission range is 0,522–18 um, The width of the forbidden range is 2.38 eV, resistance to laser radiation is 5.35 J/sq.cm. Scientific research shows that these crystals are capable of generating pulses ...

Specifications

Crystal Type: N/A
Phase Mathcing Type: Type II
Mounting: Unmounted
Width: 10 mm
Height: 10 mm
HgGa2S4 is a negative single axis crystal: no>ne, tetragonal syngony. The transparency region of this crystal is between 0.5 and 13.  Nonlinear coefficient is 26.8 pm/W. Birefringence ne-no = -0.053. Thermal Conductivity is 0.028 W/ cm-K. The laser resistance is 1J /sq.cm.HgGa2S4 (рис. 8) представляет собой отрицательный ...

Specifications

Crystal Type: N/A
Phase Mathcing Type: Type II
Mounting: Unmounted
Width: 8 mm
Height: 8 mm
Lithium Thioindate (LiInS2 or LIS) is a remarkable ternary semiconductor known for its unique crystallization with mm2 symmetry. This advanced material boasts a large nonlinear optical (NLO) coefficient, positioning it closely alongside other notable compounds such as AgGaS2 and AgGaSe2, albeit with distinct crystal structures. One ...

Specifications

Crystal Type: AgGaS2 (Silver Gallium Sulfide)
Phase Mathcing Type: Not Applicable
Mounting: Unmounted
Width: 8 mm
Height: 5 mm
The Periodically Poled Lithium Niobate (PPLN) crystal is an advanced material renowned for its exceptional efficiency in nonlinear wavelength conversion processes. This crystal is designed to cater to a broad spectrum of light transmission, encompassing both the Near-Infrared (NIR) and Mid-Infrared (MIR) spectral regions. Its ...

Specifications

Crystal Type: LiNbO3 (Lithium Niobate)
Width: 9 mm
Height: 9 mm
Length: 5 mm
Flatness: <= Lambda/8
Potassium Dihydrogen Phosphate (KDP) and Potassium Deuterium Phosphate (DKDP) are among the most widely-used commercial nonlinear optical (NLO) crystals, recognized for their exceptional frequency conversion and electro-optic properties. These crystals are extensively employed for second-, third-, and fourth-harmonic generation of ...

Specifications

Crystal Type: KD*P (Potassium Dideuterium Phosphate)
Phase Mathcing Type: Not Applicable
Mounting: Unmounted
Width: 100 mm
Height: 100 mm
The LiIO₃ (Lithium Iodate) nonlinear crystal is a negative uniaxial crystal renowned for its high nonlinear optical coefficient, broad transparency range (280–4000 nm), and resistance to radiation damage. These properties make it ideal for applications such as second and third harmonic generation, parametric oscillation, and ...

Specifications

Crystal Type: LiIO3 (Lithium Iodate)
Phase Mathcing Type: Not Applicable
Mounting: Unmounted
Width: 3 mm
Height: 2 mm
AgGaS2(AGS) crystal is transparent from 0.50 to 13.2 um. AGS crytal\'s high short wavelength transparency edging at 550nm is made use od in OPOs pumped by Nd:YAG laser; in numerous difference frequenty mixing experiments with diod; Ti:Sapphire, Nd:YAG and IR dye lasers covering 3-12um range;in direct infrared countermeasure systems; ...

Specifications

Crystal Type: AgGaS2 (Silver Gallium Sulfide)
Phase Mathcing Type: Type I
Mounting: Unmounted
Width: 5 mm
Height: 5 mm
AgGaSe2(AGSe) crystals have band edges at 0.73um and 18um. Its applicable transmission range 0.9-16um and wide phase matching capability provide excellent potential for OPO application when pumped by a variety of different lasers.

Specifications

Crystal Type: AgGaSe2 (Silver Gallium Selenide)
Phase Mathcing Type: Type I
Mounting: Unmounted
Width: 8 mm
Height: 8 mm
Potassium Titanyl Phosphate (KTiOPO4), commonly known as KTP, is a remarkable nonlinear optical material that stands out due to its high nonlinear coefficient and stable physical properties. This crystal is highly sought after in optical systems for its exceptional ability to double the frequency of the 1064 nm output from Nd:YAG ...

Specifications

Crystal Type: KTP (KTiOPO4)
Phase Mathcing Type: Type II, Type I
Mounting: Unmounted, Mounted
Width: 2 mm
Height: 2 mm
CRYSTECH Inc., based in Qingdao, China, is renowned for its cutting-edge optical products. Located on Xianshan East Rd. in the Chengyang District, CRYSTECH Inc. has established itself as a leader in the optical industry. With a commitment to quality and innovation, the company offers a wide range of products designed to meet the ...

Specifications

Crystal Type: KTA (KTiOAsO4)
Phase Mathcing Type: Type II, Type I
Mounting: Unmounted, Mounted
Width: 2 mm
Height: 2 mm
Welcome to Crystech, your trusted provider of high-quality optical crystals. One of our flagship products is the BBO (β-BaB2O4), a beta-barium borate crystal renowned for its exceptional optical properties. Grown using the flux method, BBO is a negative uniaxial crystal with a unique refractive index characteristic, where the ...

Specifications

Crystal Type: BBO (Beta Barium Borate)
Phase Mathcing Type: Type II, Type I
Mounting: Unmounted, Mounted
Width: 3 mm
Height: 3 mm
A complete range of nonlinear crystals manufactured and sold by Crystech. We provide a wide selection of nonlinear crystals tailored to customers\' needs in laser optics.Please use the REQUEST QUOTE button to contact us. 

Specifications

Crystal Type: BBO (Beta Barium Borate), BIBO (BiB3O6), KTA (KTiOAsO4), KTP (KTiOPO4), KD*P (Potassium Dideuterium Phosphate), LiNbO3 (Lithium Niobate)
Phase Mathcing Type: Type I, Type II
Mounting: Mounted, Unmounted
Width: 2 mm
Height: 2 mm

Frequently Asked Questions

Nonlinear crystals are optical materials with a refractive index that changes with the intensity of light. They are used in nonlinear optics, a branch of optics that studies the behavior of light in nonlinear media.

Nonlinear crystals work by altering the properties of light such as frequency, phase, or amplitude in a nonlinear way. When intense light passes through these crystals, they can generate new frequencies, amplify signals, or change the speed of light.

Common materials used for nonlinear crystals include Lithium Niobate (LiNbO3), Beta Barium Borate (BBO), Potassium Titanyl Phosphate (KTP), and Potassium Dihydrogen Phosphate (KDP).

Second harmonic generation (SHG) is a nonlinear optical process where two photons combine within a nonlinear crystal to create a new photon with twice the frequency and half the wavelength of the original photons. This is commonly used to change the color of laser light.

Phase matching is a condition where the phase velocities of different waves interacting within a nonlinear crystal are synchronized. This is essential for efficient energy transfer between the waves and is crucial for processes like second harmonic generation.

Nonlinear crystals are widely used in laser systems for frequency conversion, in telecommunications for signal amplification and wavelength generation, and in research for studies like ultrafast spectroscopy and quantum computing.

Choosing the right nonlinear crystal involves considering factors like the nonlinear coefficient, transparency range, phase matching conditions, thermal conductivity, and the specific requirements of the application.

The future of nonlinear crystals in photonics is promising with ongoing research in finding new materials with higher nonlinear coefficients, development of hybrid materials, and exploring applications in areas like quantum technology and ultrafast optics.

Yes, nonlinear crystals are used in medical applications such as laser surgery and medical imaging. For example, in ophthalmology, frequency-doubled lasers are used for precise procedures on the eye.

In telecommunications, nonlinear crystals are vital for optical signal processing, including amplification, frequency conversion, and compensation for signal dispersion in optical fibers. They enable high-speed and high-capacity optical communication networks.

Nonlinear Crystals: A Comprehensive Overview

Nonlinear crystals are at the forefront of modern photonics, playing a crucial role in a plethora of applications ranging from telecommunications to laser technology. These materials are distinct due to their ability to alter the properties of light in nonlinear ways, as opposed to the linear interaction found in regular optical materials. In this article, we delve into the intricacies of nonlinear crystals, explore their applications, and consider the advancements in this dynamic field.

Understanding Nonlinear Optics

The Concept: To fully comprehend nonlinear crystals, it's imperative to grasp the concept of nonlinear optics. Typically, when light interacts with a medium, the response of the medium is directly proportional to the intensity of the light. However, in nonlinear optics, the relationship is not linear. When light of high intensity interacts with a nonlinear material, it can change frequency, phase, or amplitude in a way that is not directly proportional to the input.

Nonlinear Optical Effects: In nonlinear materials, several optical phenomena can be observed. Some of the most notable are:

  • Second Harmonic Generation (SHG): A process where two photons with the same frequency combine to generate a new photon with twice the frequency and half the wavelength of the initial photons.
  • Sum and Difference Frequency Generation (SFG/DFG): Phenomena where photons interact to produce a photon with a frequency equal to the sum or difference of their frequencies.
  • Optical Parametric Amplification (OPA): A process where a photon is split into two photons with lower energies, where the sum of their energies is equal to the energy of the original photon.

Nonlinear Crystals – The Building Blocks

Material Properties: Nonlinear crystals are specially engineered materials that exhibit strong nonlinear optical properties. The efficiency of nonlinear interactions is characterized by the nonlinear coefficient of the crystal. Common materials include Lithium Niobate (LiNbO3), Beta Barium Borate (BBO), and Potassium Titanyl Phosphate (KTP).

Selection Criteria: When selecting a nonlinear crystal for specific applications, several factors must be considered:

  • Nonlinear Coefficient: A measure of the efficiency of the nonlinear optical interaction.
  • Transparency Range: The wavelength range over which the crystal remains transparent is critical, especially for applications involving different wavelength lights.
  • Phase Matching Conditions: The ability of the crystal to maintain a consistent phase relationship between interacting waves. This is vital for efficient energy transfer.
  • Thermal Conductivity: High thermal conductivity is essential for applications with high-intensity light to dissipate heat effectively.

Applications of Nonlinear Crystals

Laser Frequency Conversion: One of the most prevalent applications of nonlinear crystals is in laser frequency conversion. For example, green lasers often use SHG to convert infrared light from a diode laser into green light.

Telecommunication: Nonlinear crystals are instrumental in optical communication systems. They are used to amplify signals, compensate for dispersion, and even generate new frequencies for wavelength-division multiplexing.

Quantum Computing and Information: The generation and manipulation of quantum states of light, vital for quantum computing and information, are made possible through nonlinear optical processes within nonlinear crystals.

Future Prospects and Advancements

As photonic technologies continue to evolve, the demand for more efficient and versatile nonlinear crystals increases. Research is actively being conducted to find new materials with higher nonlinear coefficients and broader transparency ranges. Hybrid materials and meta-materials are also an area of active research that can potentially revolutionize the capabilities of nonlinear crystals.

Conclusion

Nonlinear crystals are indispensable in modern photonic applications. Through their unique ability to interact with light in non-linear ways, they have found utility in lasers, telecommunications, and emerging fields like quantum information processing.

Did You know?

Nonlinear crystals are the linchpins in the world of advanced optics and photonics. They are crucial in applications that involve frequency conversion, sum or difference frequency generation, and optical parametric processes. What makes them so special? It’s their ability to change the properties of light in remarkable ways. Common nonlinear crystals you might come across include Lithium Triborate (LBO), Beta Barium Borate (BBO), Potassium Titanyl Phosphate (KTP), Potassium Dihydrogen Phosphate & Potassium Dideuterium Phosphate (KDP & DKDP), Lithium Iodate (LiIO3), and Lithium Niobate (LiNbO3). In the infrared spectrum, crystals such as AgGaS2, AgGaSe2, GaSe, and ZnGeP2 stand out for their exceptional properties. But there's more! Some of these crystals, like DKDP, BBO, and KTP, have a dual role. They not only participate in nonlinear optical processes but also boast electro-optical properties. This dual nature makes them invaluable in applications such as Q-switching and electro-optical amplitude modulation, which are vital in precision laser systems. When it comes to selecting the right nonlinear crystal, conversion efficiency is king. This efficiency hinges on several factors including the effective nonlinear coefficient, crystal length, input power density, and phase matching. In a nutshell, these factors work together to determine how adept a crystal is at converting input light into the desired output. So, the next time you come across a cutting-edge laser or a sophisticated optical communication system, chances are, nonlinear crystals are doing the heavy lifting behind the scenes!