Description
Zinc Germanium Phosphide (ZnGeP2) is a highly regarded mid-infrared nonlinear crystal known for its exceptional properties. With a tetragonal crystal structure and a chemical formula of ZnGeP2, this crystal exhibits a significant nonlinear susceptibility, approximately 160 times larger than that of KDP (Potassium Dihydrogen Phosphate), with a d36 value of around 75 pm/V. This makes it an ideal choice for applications requiring efficient frequency conversion.
ZnGeP2 is celebrated for its broad optical transparency range, spanning from 0.74 to 12 micrometers. This wide range, combined with a high laser damage threshold, makes it particularly suited for producing near-infrared tunable lasers. The crystal's high thermal conductivity further enhances its performance, ensuring stability and efficiency in various optical applications.
The material's high nonlinear coefficient and phase-matching capabilities over a broad spectral region make it a promising candidate for mid-infrared devices, including second-harmonic generation (SHG), optical parametric oscillators (OPO), and optical parametric amplification (OPA). Its ability to maintain high performance under different conditions solidifies its role as a critical component in advanced optical systems.
ZGP Nonlinear Crystal
Specifications
Crystal Type: | ZnGeP2 (ZGP) |
---|---|
Phase Mathcing Type: | Not Applicable |
Mounting: | Unmounted |
Width: | 7 mm |
Height: | 5 mm |
Length: | 15 mm |
Flatness: | <= Lambda/10 |
Surface Quality (Scratch-Dig): | 20-10 |
AR Coating: | One side |
Chemical Formula: | ZnGeP2 |
Thermal Conductivity: | 180 W/m/K |
SHG Phase Matchable Range: | 3177 ∼ 10357nm (Type I) |
NLO Coefficients Type Ⅰ: | deeo=d36 sin2θcos2φ |
NLO Coefficients Type Ⅱ: | doeo=deoo=d36 sinθsin2φ |
Damage Threshold At 2.79 Um: | 30 GW/cm2 (150 ps) |
Damage Threshold At 10.6 Um: | 1 GW/cm2 (2 ns) |
Transparency Range: | 0.74 – 12 um |
Features
- Chemical Formula: ZnGeP2
- Crystal Structure: Tetragonal, 42m
- Lattice Parameters: a = b = 5.467Å, c = 12.736Å
- Mass Density: 4.16 g/cm3
- Mohs Hardness: 5.5
- Melting Point: About 1040°C
- Thermal Conductivity: 180 W/m/K
- Birefringence: Positive uniaxial
- Thermal Expansion Coefficient: β|| = 5×10-6/K; β⊥ = 7.8×10-6/K
- Phase Matching: Broad spectral region
Applications
- OPA (Optical Parametric Amplification): Utilized for amplifying optical signals in the mid-infrared range.
- SHG (Second-Harmonic Generation): Converts one frequency of light into its second harmonic, effectively doubling the frequency.
- OPO (Optical Parametric Oscillators): Used for generating coherent light across a wide range of frequencies.
- SFG (Sum-Frequency Generation): Combines two input frequencies to produce a new frequency, useful in spectroscopy and laser technology.
Frequently Asked Questions
What are the experimental values of phase-matching angle?
What are the properties of ZnGeP2 crystal?
What is the damage threshold of ZnGeP2 crystal?
What is the nonlinear susceptibility of ZnGeP2 crystal?
What is ZnGeP2 crystal used for?
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